Analysis of phase separation in high performance pbtepbs. While nanocrystalline materials have already led to substantially higher thermoelectric efficiencies, further improvements are expected to arise from precise chemical engineering of nanoscale building blocks and interfaces. Recent developments in nanostructured materials for high. Rationally designing highperformance bulk thermoelectric. Toward highperformance nanostructured thermoelectric. A decrease in ag content causes a great reduction in thermal conductivity and a prominent increase in zt value. Analysis of phase separation in high performance pbtepbs thermoelectric materials. Shenzhen key laboratory of thermoelectric materials, department of physics, south university of science and technology of china, shenzhen, 518055 china. Dyckc and clemens burdaa received 20th april 2011, accepted 11th july 2011. Toward highperformance nanostructured thermoelectric materials. Nanostructured thermoelectric materials springerlink. Identifying the specific nanostructures responsible for. This work opens opportunities of searching for high performance thermoelectric film for flexible thermoelectric devices.
Our recent discovery of phonon glass behaviour in asite deficient perovskite oxides and silicon nano films demonstrates that high performance thermoelectric materials can be designed using a cation vacancy engineering. Thermoelectric properties of nanostructured feal alloy prof. Thermoelectric materials promise to create additional efficiencies in energy management by harvesting the energy of waste heat and converting it to electricity. Towards high performance nanostructured thermoelectric. In 1990s, thermoelectric community is encouraged to reinvestigate advanced thermoelectric materials with high performance for thermoelectric power generation and cooling applications.
The performance of a te material is characterised by its figure of merit zt s 2. To achieve this, i have developed different approaches with the purpose to enhance the transport properties of the materials and to overcome the. In the first part of this talk, i will discuss the manufacturing of nanostructured bulk thermoelectric materials at large scale with improved thermoelectric. Fundamental studies on thermomechanical properties of. Thermoelectric devices allow direct conversion of heat into electricity and vice versa, holding great potential for heat management, precise temperature control and energy harvesting from ubiquitous temperature gradients. High performance ntype ag2se film on nylon membrane for. The samples that were most optimized with the resulting composition bi0. Over the past ten years, the exploration of highperformance thermoelectric materials has attracted great attention from both an academic research perspective and with a view to industrial. The thermoelectric performance of devices depends primarily on the type of materials used, and on their properties. Highperformance nanostructured thermoelectric materials jingfeng li1, weishu liu 1,2, lidong zhao1,2 and min zhou1,3 tsinghua university, china thermoelectric eff ects enable direct conversion between thermal and electrical energy and provide an alternative route for. Abstract highperformance nanostructured ag 1 x pb 22.
We begin with the fundamental stratagem of achieving the greatest thermoelectric figure of merit zt of a. Bismuth sulfide bi 2 s 3 polycrystalline bulks with a high relative density 90% were fabricated by combining mechanical alloying ma and spark plasma sintering sps. Bi2te3 nanoplates were synthesized by the reaction between bismuth thiolate and trinoctylphosphine telluride in oleylamine. The main issue with oxides is the high thermal conductivity. Introduction to a great extent, the development of civilization has evolved with the technological advent of energy production, storage, delivery, and use. Performance thermoelectricity in nanostructured earth. Thermoelectric energy conversion technique has been used as the power supply for the deepspace exploring missions, now showing notable advantages to harvest the widely distributed waste heat and convert the abundant solar energy into electricity. Continue to develop the materials to increase zt and understand compositional changes and the effect on the temperature range of zt.
Nanostructured materials and thermoelectrics have been the subject of signi cant research in recent years 5, and it is a challenging topic combining materials science, nanoscience and physics. Nanostructure and high thermoelectric performance in. Enhancement of thermoelectric performance of ntype bi2te3. Recent progress in nanostructured thermoelectric materials. We report promising thermoelectric properties of the rock salt pbsepbs system which consists of chemical elements with high natural abundance. A teg is fabricated using highefficiency nanostructured thermoelectric materials. This highlight discusses recent trends in the search for new highefficiency thermoelectric materials. The efficiency of thermoelectric devices is primarily governed by three interrelated material parameters.
Highperformance thermoelectric nanocomposites from. Systems and methods of manufacturing a thermoelectric, high performance material by using ballmilling and hot pressing materials according to various formulas, where some formulas substitute a different element for part of one of the elements in the formula, in order to obtain a figure of merit zt suitable for thermoelectric applications. Herein, we report the synthesis of multiscale nanostructured ptype bi,sb2te3 bulk materials by meltspinning single elements of bi, sb, and te followed by a spark plasma sintering process. Towards high performance nanostructured thermoelectric materials. Thermoelectric te materials have the capability of converting heat into electricity, which can improve fuel efficiency, as well as providing robust alternative energy supply in multiple applications by collecting wasted heat, and therefore, assisting in finding new energy solutions.
Nanostructured high temperature bulk thermoelectric energy. The fundamental problem in designing new materials for thermoelectric applications lies in the interdependence of the three key properties figure 3 that determine the figureofmerit and hence performance. Doping with pbcl2, excess pb, and bi gives ntype behavior without significantly perturbing the cation sublattice. Nanostructure approach for highperformance thermoelectrics, photovoltaics, and biosensing z. Nanostructured materials are key for future thermoelectric devices because they may make it possible to decouple thermal and electronic transport, which is crucial for achieving a high efficiency energy conversion. Highperformance nanostructured thermoelectric materials.
Nanostructured hightemperature bulk thermoelectric. The goal of this project is to investigate the inpile performance of highefficiency nanostructured thermoelectric materials, and develop highperformance and irradiationresistant thermoelectric devices for inpile power harvesting and sensing. Thermoelectric materials offer considerable attractions in the pursuit of a more efficient use of existing energy resources, as they may be used to construct powergeneration devices that allow useful electrical power to be extracted from otherwise waste heat. For this reason, there is a revival of interest in the development of highperformance thermoelectric materials and the relevant thermoelectric theory. Thermoelectric materialsstrategies for improving device.
Novel nanostructured highperformance thermoelectric. Materials or advanced sensors for nuclear applications abstract. Exploring nanostructured thermoelectric materials is not only useful searching for the next generation of thermoelectric materials exceeding zt2. Nanostructured high temperature bulk thermoelectric energy conversion for efficient waste heat recovery dr. Special issue on thermoelectric properties of nanostructured materials. The microstructural and thermoelectric te properties were investigated with a. Recent advances on thermoelectric materials abstract by converting waste heat into electricity through the thermoelectric power of solids without producing greenhouse gas emissions, thermoelectric generators could be an important part of the solution to todays.
Such applications often require materials manufacturing at large scale and low cost. The widespread use of thermoelectric components is presently limited by the low figureofmerit of presently known materials. Putatunda, shashank nellikuppam department of chemical engineering and materials science, wayne state university. The objective of the phase 1 proposal was to demonstrate a new route to the realization of highly efficient bulk thermoelectric materials. There has been a renaissance of interest in exploring highly efficient thermoelectric materials as a possible route to address the worldwide energy generation, utilization, and management. View the article pdf and any associated supplements and figures for a period of 48 hours. This discovery sets the stage for use of a new nanocomposite approach in developing highperformance lowcost bulk thermoelectric materials. According to takayamas work, a highperformance thermoelectric generator based on sb 2 te 3 and bi 2 te 3 films had been fabricated, exhibiting an open circuit voltage of 32 mv and maximum output power of 0. W by applying a temperature difference of 28 k, the basic films were deposited by magnetron sputtering. The main advantages of a peltier cooler compared to a vaporcompression refrigerator are its lack of moving parts or. Thus, despite the great extent of dissolution of pbs in pbse, the transport properties in this system, such as carrier mobilities and. While nanocrystalline materials have already led to substantially higher thermoelectric efficiencies, further improvements are ex pected to arise from precise chemical engineering of nanoscale building blocks and interfaces. Nanostructures having high performance thermoelectric. Nanostructured thermoelectric materials are materials that contain nanoscale constituents and exhibit enhanced thermoelectric performance due to nanoscale phenomena.
Introduction to materials science chapter 19, thermal properties 18 quest for good thermoelectric te materials nanostructured materials a chance to disconnect the linkage between the thermal and electrical transport by controlling scattering mechanisms li et al. High performance nano powder manufacturer thermoelectric materials tm bi2te3 bi2se3 sb2te3 bi2te2. We herein report on the largescale synthesis of ultrathin bi2te3 nanoplates and subsequent spark plasma sintering to fabricate ntype nanostructured bulk thermoelectric materials. As a refrigeration technology, peltier cooling is far less common than vaporcompression refrigeration. Rapid synthesis of highperformance thermoelectric materials directly from natural mineral tetrahedrite volume 3 issue 3 xu lu, donald t. Highthermoelectric performance of nanostructured bismuth.
Recent advances in highperformance bulk thermoelectric. To develop highperformance te devices, it requires not only a good. Thermoelectric materials can be used as refrigerators, called thermoelectric coolers, or peltier coolers after the peltier effect that controls their operation. Thermoelectric power generation modules assembled using the tifsbased high performance n and p type materials show the largest thermoelectric conversion efficiency of 5. Special issue highperformance thermoelectric materials. Recent developments of highperformance nanostructured thermoelectric te materials show that these materials have much higher conversion efficiencies than the.
View enhanced pdf access article on wiley online library html view. Highperformance bulk thermoelectrics with allscale. The efficient conversion between thermal and electrical energy by means of durable, silent and scalable solidstate thermoelectric devices has been a long standing goal. With about twothirds of all used energy being lost as waste heat, there is a compelling need for highperformance thermoelectric materials that can directly and reversibly convert heat to. Thermoelectric te materials facilitate direct heattoelectricity conversion. Ace082 this presentation does not contain any proprietary, confidential, or otherwise restricted information. Here we present a simple and versatile bottomup strategy based on the assembly of colloidal nanocrystals to produce.